A paleoenvironmental reconstruction of Laguna Babícora, Chihuahua, Mexico based on ostracode paleoecology and trace element shell chemistry     

Manuel R. Palacios-Fest  Ana Luisa Carreño  José R. Ortega-Ramírez  Guillermo Alvarado-Valdéz 《Journal of Paleolimnology》2002,27(2):185-206

Paleoecology of Laguna Babícora, Chihuahua, Mexico was reconstructed using ostracode faunal assemblages and shell chemistry. The paleolimnological record is used to show the magnitude of paleoclimatic changes in the area from 25,000 years to the present.Faunal assemblages consist of four species of the genus Limnocythere: L. sappaensis, L. ceriotuberosa, L. bradburyi and L. platyforma, all associated with Candona caudata, Candona patzcuaro and Cypridopsis vidua. A paleosalinity index developed from these assemblages indicates that the lake's salinity fluctuated frequently from oligo- to meso-haline conditions during the last 25,000 years. This pattern and low salinity range are in good agreement with modern TDS (here used as an indicator of salinity) values recorded from 26 wells and one spring from the area (258–975 mg l^–1). To estimate paleotemperature we examined the trace element content (Mg/Ca ratios) from individual valves of L. ceriotuberosa and L. platyforma, the two species most commonly recorded in Laguna Babícora.Shell Mg/Ca ratios of 204 specimens of these two species were used to estimate water temperature (Mg/Ca) by means of experimental standard coefficients. Our data show that paleowater temperature ranged from 5.6–21.3 °C (with 2 values ranging from 0.2–4.8 °C), which suggest a close correlation with atmospheric temperatures around the lake. These results are in good agreement with a modern mean winter temperature (3.5 °C) and mean summer temperature (20 °C) recorded in the area between 1970 and 1980.  相似文献   

Cenozoic Plate interaction of the Australia and Philippine Sea Plates: “hit-and-run” tectonics     

Manuel Pubellier  Jason Ali  Christophe Monnier 《Tectonophysics》2003,363(3-4):181-199

Recent studies in northwest New Guinea have shown the presence of at least two marginal basins of different age, both of which formed in back-arc settings. The older basin opened between the Middle Jurassic and Early Cretaceous, a remnant of which is now preserved as the New Guinea Ophiolite. Its obduction started at 40 Ma and it was finally emplaced on the Australian margin at 30 Ma. The younger basin was active during the Oligocene to Middle Miocene and was obducted in the Early Pliocene. Studies of the western edge of the Philippine Sea also reveal an important deformation of the Philippine arc in the Oligocene, which hitherto has remained unexplained. Using information from these systems, paleomagnetic results, kinematic reconstructions and geochemistry of the supra-subduction ophiolite, we present a plate model to explain the region's Eo–Oligocene development. We suggest that an extensive portion of oceanic crust extended the Australian Plate a considerable distance north of the Australian Craton. As Australia began its steady 7–8 cm/year northward drift in the Early Eocene, this lithosphere was subducted. Thus, the portion of the Philippine Sea Plate carrying the Taiwan–Philippine Arc to its present site may have actually been in contact with the ophiolite now in New Guinea and obduction led to deformation of the Philippine Sea Plate itself. Neogene Plate kinematics transported the deformed belt in contact with the Sunda block in the Late Miocene and Pliocene. This interpretation has implications for the origin for the Philippine Sea Plate and the potential incorporation of continental fragments against its boundaries.  相似文献   

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle     

Manuel Moreira  Jerzy Blusztajn  Joshua Curtice  Stan Hart  Henry Dick  Mark D. Kurz 《Earth and Planetary Science Letters》2003,216(4):635-643

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.  相似文献   

The impact of hydrological changes on travertine deposits related to thermal springs in the Pamukkale area (SW Turkey)   总被引：2，自引：0，他引：2  

Dilsiz  Cüneyt  Marques  José Manuel  Carreira  Paula Maria Mimo 《Environmental Geology》2004,45(6):808-817

Pamukkale thermal waters (35 °C), exhibiting calcium-bicarbonate-sulfate composition and high carbon dioxide concentration, are of a predominantly meteoric origin. The meteoric fluid, circulating through faults and fractures, is heated by magmatic intrusions at great depth, and ascends from deep reservoirs to the surface. Mixing with relatively cold groundwater in the near surface zone promotes different saturation conditions with respect to calcium carbonate that later precipitates at depth and/or the surface. Dissolution-deposition processes of calcium carbonate both at surface and depth environments may help to reconstruct past climate direction in the field. During wet climate conditions a high-rate of calcium carbonate accumulation would be expected to occur at the surface because thermal fluid would be under-saturated with respect to calcium carbonate at depth because of a relatively higher mixing ratio with cold groundwater. During dry climate conditions the thermal fluid would be super-saturated at depth because of the highly acidic environment. Hydrometeorological studies reveal that the annual precipitation at the Pamukkale hydrothermal field tends to decrease with time. This climatic change in the area was also detected from geological records. While humid climate conditions prevailed during the late Quaternary, the area has recently been affected by arid/semi-arid climate conditions, followed by some episodic transitions. This study has shown how the system has possibly reacted to different climate conditions since antiquity.  相似文献   

Noble gases in the earth's mantle     

D.P. Thompson  A.R. Basu  E.W. Hennecke  O.K. Manuel 《Physics of the Earth and Planetary Interiors》1978,17(2):98-107

The abundances and isotopic compositions of noble gases in two samples from ultramafic xenoliths in alkali basalt, a young kaersutitic amphibole separated from a peridotite xenolith from Dish Hill, California and an ancient whole-rock lherzolite xenolith from Baja California, are reported and compared with the results of analyses on other mantle samples. In addition to previously recognized excesses of ³He and ¹²⁹Xe, our results indicate that ambient gases in the mantle show a general enrichment of the lighter-mass nonradiogenic isotopes of Ar, Kr and Xe, and Ar with ⁴⁰Ar/³⁶Ar = 3 · 10².  相似文献   

Groundwater behaviour in Madeira, volcanic island (Portugal)     

Susana Nascimento Prada  Manuel Oliveira da Silva  José Virgílio Cruz 《Hydrogeology Journal》2005,13(5-6):800-812

Madeira Island is a hot-spot originating from a mantle plume. K-Ar age determinations indicate that the emerged part of the island was generated during Post-Miocene times 6000–7000 years B.P. Groundwater occurs in perched-water bodies, spring discharge from them is high, about 3,650 l/s; in dike-impounded water and basal groundwater. Basal groundwater is exploited by tunnels (1,100 l/s) and wells (1,100 l/s). Hydraulic gradients range from 10^–4 to 10^–2 and transmissivity ranges from 1.16×10^–2 to 2.89×10^–1 m²/s, indicating the heterogeneity of the volcanic aquifers. Water mineralisation is variable, and electrical conductivity ranges from 50 to 3,300 S/cm. There is a difference between groundwater discharging from perched-water bodies (43–201 S/cm) and from basal groundwater (109–3,300 S/cm). Groundwater average pH is 7.37, with waters acid to slightly alkaline (6.13–8.4), and generally cold. Nevertheless, a few samples associated with fault zones can be classified as thermal waters.

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Resumen La Isla de Madeira tuvo origen en un punto caliente proveniente de una pluma del manto. Las dataciones K – Ar, indican que la parte emergida de la isla se formó durante en Post—Mioceno, hace unos 6000–7000 años. El agua subterránea se encuentra en acuíferos colgados, cuya descarga a través de manantiales es alta, alrededor de 3650 l/s; también como agua retenida en diques o bien como agua subterránea propiamente dicha. Esta última es explotada por túneles (1100 l/s) y pozos (1100 l/s). Los gradientes hidráulicos varían desde 10–4 hasta 10–2 y la transmisividad varía desde 1.16×10^–2 hasta 2.89×10^–1 m²/s, indicando la heterogeneidad de los acuíferos volcánicos. La mineralización de agua es variable y la conductividad eléctrica varía desde 50 mS/cm hasta 3300 mS/cm. Hay una diferencia entre el agua subterránea proveniente de acuíferos colgados (43–201 mS/cm) y aquella del acuífero principal (109–3300 mS/cm). El pH promedio para el agua subterránea es 7.37; con variación desde ácida hasta ligeramente alcalina (6.13–8.4), y es generalmente fría. Sin embargo unos pocos ejemplos asociados con zonas de falla, pueden ser clasificados como agua termal.

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Résumé Lîle de Madeira est un point chaud, provenant dun panache mantélique. Les datations par la méthode de K-Ar indiquent que la part émergée de lîle a été générée pendant le Post Miocène, il y a 6000–7000 ans. Les eaux souterraines sont cantonnées dans des aquifères perchées qui se déchargent par des sources à grands débits, avec des valeurs dapproximativement de 3500 l/s, ainsi que dans les dikes. Une importante quantité des eaux souterraine se trouve sur la forme deau de fonds, formant une nappe basale, qui est exploitée par des tunnels (1100 l/s) et par des puits (1100 l/s). Les gradients hydrauliques ont des valeurs dans lintervalle de 10^–2 à 10^–4, tandis que les transmissivités se rangent entre 1.16×10^–2 m²/s et 2.81×10^–1 m²/s, ce quindique la hétérogénéité de laquifère volcanique. La minéralisation des eaux est aussi variable avec des conductivités électriques qui se rangent ente 50 mS/cm et 3300 mS/cm. Il y a une différence entre la conductivité des eaux provenant des aquifères perchées (30–201 mS/cm) par rapport à la conductivité les eaux de la nappe basale (109–3300 mS/cm). Le pH moyen est de 7.37 avec des valeurs de 6.13 pour les eaux acides et de 8.4 pour les eaux à faible alcalinité. En général il sagit des eaux froides, mais quelques échantillons provenant des zones faillées peuvent être classifiés comme des eaux thermales.

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Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: VII. Carbonate isotope geochemistry as a record of riverine runoff     

David?L.?DettmanEmail author  Manuel?R.?Palacios-Fest  Hudson?H.?Nkotagu  Andrew?S.?Cohen 《Journal of Paleolimnology》2005,34(1):93-105

Evaporation dominates the removal of water from Lake Tanganyika, and therefore the oxygen isotope composition of lake water has become very positive in comparison to the waters entering the lake. The surface water in Lake Tanganyika has remained relatively unchanged over the last 30 years with a seasonal range of +3.2 to +3.5 VSMOW. Water from small rivers entering the lake seems to have a ¹⁸O value between –3.5 and –4.0, based on scattered measurements. The two largest catchments emptying into the lake deliver water that has a ¹⁸O value between these two extremes. This large contrast is the basis of a model presented here that attempts to reconstruct the history of runoff intensity based on the ¹⁸O of carbonate shells from Lake Tanganyika cores. In order to use biogenic carbonates to monitor changes in the ¹⁸O of mixing-zone water, however, the oxygen isotope fractionation between water and shell carbonate must be well understood. The relatively invariant environmental conditions of the lake allow us to constrain the fractionation of both oxygen and carbon isotope ratios. Although molluskan aragonitic shell ¹⁸O values are in agreement with published mineral-water fractionations, ostracode calcite is 1.2 more positive than that of inorganic calcite precipitated under similar conditions. Ostracode shell ¹⁸O data from two cores from central Lake Tanganyika suggest that runoff decreased in the first half of this millennium and has increased in the last century. This conclusion is poorly constrained, however, and much more work needs to be done on stable isotope variation in both the waters and carbonates of Lake Tanganyika. We also compared the ¹³C of shells against predicted values based solely on the ¹³C of lake water dissolved inorganic carbon (DIC). The ostracode Mecynocypria opaca is the only ostracode or mollusk that falls within the predicted range. This suggests that M. opaca has potential for reconstructing the carbon isotope ratio of DIC in Lake Tanganyika, and may be a useful tool in the study of the history of the lakes productivity and carbon cycle.  相似文献   

Surface area, porosity and water adsorption properties of fine volcanic ash particles   总被引：1，自引：1，他引：0  

Pierre Delmelle  Frédéric Villiéras  Manuel Pelletier 《Bulletin of Volcanology》2005,67(2):160-169

Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, a_s, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated a_s values in the range 1.1–2.1 m²/g, except in one case where a a_s of 10 m²/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption a_s values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10^–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert  相似文献   

On the Intensity Thresholds of the Network and Plage Regions     

Michael Steinegger  Jose A. Bonet  Manuel Vázquez  Antonio Jiménez 《Solar physics》1998,177(1-2):279-286

A period of minimum solar activity in April and May 1996 was used to analyze full-disk CaK spectroheliograms with the aim of deriving the intensity thresholds of the quiet network and the plages by applying the so-called inflexion point method. The average network intensity threshold is found to be influenced mainly by the seeing, whereas the average plage threshold shows an increasing trend from disk center towards the solar limb. Both parameters are compared with the results of other authors.  相似文献   

The enigma of helium and anomalous xenon     

Oliver K. Manuel 《Icarus》1980,41(2):312-315

Isotopically anomalous xenon in chondrites is closely associated with low-Z noble gases, but there is no helium (or neon) in the noble gas component with normal xenon. The correlation of elemental and isotopic heterogeneities in meteoritic noble gases places stringent limits on the origin of isotopically anomalous elements in meteorites and on the formation of the solar system.  相似文献